期刊
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
卷 77, 期 9, 页码 1001-1005出版社
AMER OIL CHEMISTS SOC A O C S PRESS
DOI: 10.1007/s11746-000-0158-6
关键词
estimation method; fatty acid; liquid specific heat capacity; Rowlinson-Bondi equation; triacylglycerol; vegetable oil
The liquid specific heat capacity of fatty acids can be accurately estimated using the Rowlinson-Bondi method. This method requires the specific heat capacity of ideal gases, the critical temperature, and the acentric factor for each acid. The liquid specific heat capacity of triacylglycerols acid vegetable oils can be estimated using mixture properties corresponding to the fatty acid composition and a correction factor, which accounts for the triacylglycerol form. The experimental data of triacylglycerols were used to produce the generalized correction factor. The estimated values were compared to experimental values and the error was found to be within +/- 5%.
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