期刊
COORDINATION CHEMISTRY REVIEWS
卷 206, 期 -, 页码 321-368出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00299-X
关键词
disiloxanediolates; metallasilsesquioxanes; silsesquioxanes; lanthanides; actinides; early transition metals
Two modern areas of metallasiloxane chemistry are reviewed. The first part deals with the preparation and structural characterization of the first f-element compounds derived from tetraphenylsisiloxanediol. In the second part recent developments in the chemistry of polyhedral metallasilsesquioxanes are surveyed, with special emphasis being placed on early transition metal and f-element derivatives. Also highlighted are applications of these species in catalysis research. (C) 2000 Elsevier Science S.A. AU rights reserved.
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