期刊
POLYMER DEGRADATION AND STABILITY
卷 67, 期 3, 页码 437-447出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0141-3910(99)00142-1
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A PP/PE copolymer was successively flame retarded using Mg(OH)(2), then using brominated trimethylphenyl indane associated with Sb2O3 (Br/Sb), and finally using blends of equal weights of this last combination with Mg(OH)(2) or talc-containing non-hydrated fillers. Decompositions of pure and additive-containing copolymer were studied by DTA/TGA coupled with FTIR. A good correlation exists between the maxima of Gram-Schmidt curves and the derivatives of TGA curves. The coupling of techniques shows that the incorporation of the Br/Sb flame retardant limits strong exothermic phenomena due to sample ignition. In the case of Mg(OH)(2) associated with Br/Sb, the decomposition of the hydrated mineral occurs at a lower temperature than the reaction between brominated trimethylphenyl indane and Sb2O3. This delays the action of Br/Sb flame retardant towards higher temperatures, improving the thermal stability of the polymer. A good agreement is also found between DTA/TGA-FTIR conclusions and fire resistance tests carried out on standardized samples. When magnesium hydroxide is replaced by the fillers, the interest in using a purr talc, which appeared in fire resistance tests, is not strongly confirmed by DTA/TGA-FTIR. This discrepancy may be ascribed to the reduced influence of mass diffusion phenomena due to the small weight of the sample used in thermal analysis experiments. (C) 2000 Elsevier Science Ltd. All rights reserved.
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