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A novel FeS cluster in Fe-only hydrogenases

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TRENDS IN BIOCHEMICAL SCIENCES
卷 25, 期 3, 页码 138-143

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ELSEVIER SCIENCE LONDON
DOI: 10.1016/S0968-0004(99)01536-4

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Many microorganisms can use molecular hydrogen as a source of electrons or generate it by reducing protons. These reactions are catalysed by metalloenzymes of two types: NiFe and Fe-only hydrogenases. Here, we review recent structural results concerning the latter, putting special emphasis on the characteristics of the active site.

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