期刊
TRANSITION METAL CHEMISTRY
卷 25, 期 4, 页码 369-373出版社
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1007055304150
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Novel Pd-II and Pt-II complexes of substituted o-hydroxyacetophenone-glycine have been synthesized, and characterized by conductivity measurements, i.r., electronic and H-1-n.m.r. spectra. The spectral data indicate that the ligands are monobasic bidentate, coordinating through imino nitrogen and the carboxylate group. A four coordinate square planar configuration has been proposed for all the complexes. The ligands, as well as their Pd-II and Pt-II complexes, exhibit potent cytotoxic activity against Ehrlich ascites tumour cells in vitro, but appear to be more active in vivo.
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