期刊
CHEMCATCHEM
卷 7, 期 1, 页码 62-64出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402527
关键词
reductive amination; aldehyde; ketone; heterogeneous catalysis; cobalt catalyst
资金
- German Federate State of Mecklenburg-Western Pomerania
- Bundesministerium fur Bildung und Forschung (BMBF)
Heterogenized non-noble metal-based catalysts allow for cost-efficient and environmentally benign hydrogenations. Here, we have developed a straightforward reductive amination methodology using molecular hydrogen in the presence of a Co3O4/NGr@C catalyst system. Various carbonyl compounds were transformed with secondary amines to the corresponding tertiary amines with good to excellent yields and selectivity. The Co3O4/NGr@C catalyst is recycled up to five times without significant loss of activity.
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