期刊
CHEMCATCHEM
卷 6, 期 12, 页码 3355-3359出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402604
关键词
biomass; heterogeneous catalysis; iron; oxidation; radical reactions
The production of gluconic acid from D-glucose represents an attractive target for industry. In this work, we propose an efficient, eco-friendly, and selective method to oxidize D-glucose with aqueous H2O2 in the presence of FeSO4 as a catalyst. The reaction was improved significantly under ultrasonic (US) activation, which led to excellent yields in only a few minutes. In addition, we determined that the reaction occurred through a sono-Fenton process by studying the production of hydroxyl radicals and optimizing the experimental conditions of the reaction. The energy consumption of the process was also investigated in this study.
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