期刊
CHEMCATCHEM
卷 6, 期 8, 页码 2244-2247出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402029
关键词
aldol reaction; enantioselectivity; iron; Lewis acids; surfactants
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre in Green Chemistry and Catalysis (CGCC)
- Canada Foundation for Innovation (CFI)
- Universite Laval
- NSERC
- Fonds Quebecois de la Recherche-Nature et technologies (FQRNT)
The catalytic asymmetric Mukaiyama aldol reaction in pure water was performed by using a combination of iron(II) dodecyl sulfate, a chiral bipyridine ligand, and benzoic acid. By using the obtained iron(II)-derived Lewis acid/surfactant combined catalyst, the desired products were afforded in good yields with high diastereo- and enantioselectivities.
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