期刊
CHEMCATCHEM
卷 6, 期 3, 页码 857-865出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300946
关键词
alkenes; alkynes; boron; nanoparticles; platinum
资金
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2007-65218, CTQ2011-24151]
- Generalitat Valenciana (GV) [PROMETEO/2009/002, PROMETEO/2009/039]
- FEDER
Platinum nanoparticles supported on titania efficiently catalyzed the diboration of alkynes and alkenes under solvent- and ligand-free conditions in air. The cis-1,2-diborylalkenes and 1,2-diborylalkanes were obtained in moderate to excellent yields following, in most cases, a simple filtration workup protocol. The versatility of the cis-1,2-diboronvinyl compounds was demonstrated in a series of organic transformations, including the Suzuki-Miyaura cross coupling and the boron-halogen exchange.
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