期刊
CHEMCATCHEM
卷 7, 期 3, 页码 434-440出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402642
关键词
biomimetic catalysis; CH activation; insitu analysis; methane oxidation; zeolites
资金
- UK Catalysis Hub
- EPSRC [EP/K014714/1]
- Royal Society of Chemistry
- EPSRC [EP/K014714/1, EP/K014854/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K014714/1, EP/K014854/1] Funding Source: researchfish
Developing inorganic materials that can mimic nature's ability to selectively oxidise inert CH bonds remains a topic of intense scientific research. In recent years, zeolitic materials containing Fe and/or Cu have been shown to be highly active, heterogeneous catalysts for the selective oxidation of alkanes (including methane), amongst a range of other related oxidation challenges. By using resonance-enhanced Raman spectroscopy, we demonstrate that, following high-temperature pre-treatment (activation), Fe-containing ZSM-5 possesses an active binuclear core, and forms a key FeOOH intermediate upon activation with H2O2. Both factors are reminiscent of biological oxidation catalysts, and may account for the unique ability of this material to selectively oxidise methane to methanol at low temperature.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据