期刊
CHEMCATCHEM
卷 6, 期 6, 页码 1526-1530出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402119
关键词
homogeneous catalysis; hydrogenation; hydrogen; reaction mechanisms; ruthenium
资金
- Technology Foundation STW
- Netherlands Organization for Scientific Research (NWO)
The use of hydrogen as a fuel requires both safe and robust technologies for its storage and transportation. Formic acid (FA) produced by the catalytic hydrogenation of CO2 is recognized as a potential intermediate H-2 carrier. Herein, we present the development of a formate-based H-2 storage system that employs a Ru PNP-pincer catalyst. The high stability of this system allows cyclic operation with an exceptionally fast loading and liberation of H-2. Kinetic studies highlight the crucial role of the base promoter, which controls the rate-determining step in FA dehydrogenation and defines the total H-2 capacity attainable from the hydrogenation of CO2. The reported findings show promise for the development of practical technologies that use formic acid as a hydrogen carrier.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据