4.6 Article

H-2-Induced Reconstruction of Supported Pt Clusters: Metal-Support Interaction versus Surface Hydride

期刊

CHEMCATCHEM
卷 3, 期 1, 页码 200-207

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201000324

关键词

density functional calculations; hydrides; metal-support interactions; platinum; supported catalysts

资金

  1. Agence Nationale de la Recherche (ANR) [ANR-06-CIS6-014-04]
  2. GENCI [x2010086134]
  3. CINECA (DECI/DEISA) HPC centers [91927]

向作者/读者索取更多资源

Platinum nanoparticles supported on gamma-alumina are widely used as highly dispersed heterogeneous catalysts, in particular in the presence of H-2. In the present work, an atomic-scale model for such catalysts is provided, taking into account operating conditions (temperature, hydrogen pressure), thanks to density functional theory calculations coupled to a thermodynamic model. In the absence of hydrogen, Pt-13 clusters supported on gamma-Al2O3 preferentially lie in a biplanar (BP) morphology in strong interaction with the support's surface. This structure has a strong affinity towards hydrogen. The increase of hydrogen coverage above 18 H atoms per cluster (H/Pt > 1.4) induces a reconstruction from a BP to a cuboctahedral (CUB) morphology as shown by molecular dynamics. This reconstruction is driven by the ability of the CUB structure to adsorb a significant amount of hydrogen with moderate deformation cost. Electronic analyses reveal that a hydride phase is then obtained, with a partial loss of the metallic nature of the Pt13 edifice. Our model is supported by numerous experimental data (temperature-programmed desorption, titration experiments, X-ray absorption spectroscopy). Values higher than 1 for the H/Pt ratio, as measured in previous experimental analyses, are rationalized by the reconstruction process. Moreover, in reaction conditions such as catalytic reforming, the particle remains biplanar with moderate H/Pt ratio and retains its metallic character. The catalytic conditions therefore have a drastic influence on the nature of the catalyst surface.

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