期刊
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
卷 7, 期 1, 页码 17-25出版社
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1011216832274
关键词
adsorption; diffusion; NaX zeolite; paraffins; olefins; water-thermal frequency response; activation energy
Measurements have been performed on the influence of a small amount of water on adsorption properties of alkanes (C-3 to C-6) and olefins (C-3 and C-4) in NaX zeolite. Adsorption capacity and heat of adsorption have been measured by a Volume Step method. Kinetics has been measured by Thermal Frequency Response method and the results have been compared with the results obtained by PFG-NMR. It has been found that water reduces the adsorption capacity especially at low adsorbate concentration. The heat of adsorption is slightly reduced by water. The kinetics of alkanes is always reduced by the adsorbed water. On the contrary, the diffusion kinetics of olefins is improved or remains unchanged, depending of the sorbat concentration.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据