Single particle dynamics in fluid and solid hydrogen sulphide: An inelastic neutron scattering study

Inelastic neutron scattering experiments were performed at intermediate and high momentum transfer, up to 88.2 Angstrom (-1), to study the temperature dependence;of single hydrogen mean kinetic energy in polycrystalline and liquid hydrogen;sulphide (H2S), in the temperature range 16-206 K. Values of the hydrogen mean kinetic energy were extracted, within the; impulse approximation, by fitting to the high momentum transfer data a model response function, obtained from a momentum distribution which is the orientational average of a multivariate Gaussian function. The extracted kinetic energies are compared with a harmonic model for the vibrational-and roto-translational dynamics. The model makes use of the hydrogen-projected density of states worked out from intermediate momentum transfer data, as well as of optical frequencies determined from Raman and infrared (IR) spectroscopy. A fairly good agreement is obtained in the whole temperature range, while noticeably lower values for the kinetic energy are found if a single atom momentum distribution of isotropic Gaussian shape is assumed in the model response function. (C) 2001 American Institute of Physics.