期刊
TETRAHEDRON LETTERS
卷 42, 期 1, 页码 137-140出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01904-3
关键词
radicals and radical reactions; catalysis; thiols; diols; rearrangements; carbohydrates
Cyclic benzylidene acetals derived from 1,2- and 1,3-diols undergo an efficient ring-opening redox rearrangement to give benzoate esters in the presence of a peroxide initiator and a thiol, which acts as a polarity-reversal catalyst to promote the radical-chain reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.
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