期刊
CHEMBIOCHEM
卷 10, 期 3, 页码 545-552出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cbic.200800595
关键词
biocatalysis; manganese; metalloenzymes; protein-metal hybrids; sulfide oxidation
资金
- Agence National pour la Recherche [ANR-05-Blan-0042]
- Agence Nationale de la Recherche (ANR) [ANR-05-BLAN-0042] Funding Source: Agence Nationale de la Recherche (ANR)
Artificial metalloenzymes based on the incorporation of Mn-salen complexes into human serum albumin display high efficiency and selectivity for sulfoxide production during sulfide oxidation. The reactions carried out by the artificial metallozymes are comparable to those carried out by natural biocatalysis. We have found that the polarity of the protein environment is crucial for selectivity and that a synergy between both partners of the hybrid results in the novel activity.
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