期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 20, 页码 2054-2055出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b105602f
关键词
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Intramolecular electrostatic repulsions between the local negative charge on a trifluoromethyl group and that on the ortho position of an aryl moiety of a nucleophile was found to be a controlling factor of the diastereoselectivity in a cyclopropanation reaction, in which the electrostatic repulsion was evaluated quantitatively.
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