期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 21, 期 10-11, 页码 1307-1311出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0955-2219(01)00007-3
关键词
dielectric properties; ferroelectric properties; perovskites; PLZT; spectroscopy
Wide range dielectric response (10-10(14)Hz) of three relaxor ferroelectrics: PMN, PLZT and PST is analyzed. The common features are: low phonon contribution to the high static permittivity; dielectric relaxation in a wide frequency range; widening of the relaxation times distribution with decreasing temperature down to the freezing temperature T(f), where extrapolated divergence of the mean relaxation time takes place; change of dielectric behaviour at the Burns temperature T(B). Dynamics of polar nanoclusters, which appear below T(B), is considered to be responsible for the relaxor behaviour. It enables us to define the general structure of the dielectric spectrum of relaxor ferroelectrics. Only above T(B) the fundamental dielectric contribution is due to polar phonons. Below T(B) the contributions caused by polar clusters dynamics prevail: both dipole reversal of polar cluster and fluctuations of their boundaries contribute to the dielectric response. (C) 2001 Elsevier Science Ltd. All rights reserved.
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