期刊
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
卷 -, 期 3, 页码 222-224出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b008158m
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The monomeric alkoxide (BDI)Mg((OBu)-Bu-t)(THF) and triphenylsiloxide (BDI)Zn(OSiPh3)(THF) have been prepared and characterized and shown to reversibly dissociate THF in solution on the NMR time scale; both compounds are active precursors for the ring-opening polymerization of lactide and the rate of polymerization is notably faster for the magnesium complex though in the polymerization of rac-lactide only the zinc complex shows selectivity for heterotactic tetrads.
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