期刊
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
卷 -, 期 22, 页码 2946-2957出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b107180g
关键词
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The reaction of enolates of 1,3-dicarbonyl compounds with alpha -halo-alpha, beta -unsaturated carbonyl compounds affords 2,4-diacyldihydrofuran derivatives in the presence of DBU in THF. Chemical manganese dioxide oxidation of the hydrofurans leads to 2,4-diacylfuran derivatives. Application of the protocol enables short-step syntheses of antitumor naphthofuran natural products.
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