期刊
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
卷 -, 期 8, 页码 832-837出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b009626l
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An efficient method for the synthesis of 1-thio-beta -mannopyranosides is reported. This method employs the simple, easy-to-make 2,3,4,6-tetra-O-acetyl-1-S-acetyl-1-thio-beta -D-mannopyranose as starting material to conduct an in situ selective de-S-acetylation, and subsequent S(N)2 reaction with an acceptor bearing a leaving group. The high nucleophilicity and slow anomerization of the intermediate thiol allows the synthesis of 1-thio-beta -mannopyranosides in a simple and practical manner.
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