期刊
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
卷 20, 期 1, 页码 127-132出版社
WILEY
DOI: 10.1002/etc.5620200113
关键词
aqueous solubility; dissolution thermodynamics; phthalates; sorption; surface tension
Aqueous solutions of DEP (di-ethyl), DnBP (di-n-butyl), DnH(6)P (di-n-hexyl), and DEHP (di-[2-ethyl-hexyl])phthalates have been investigated by use of surface tension measurements at temperatures between 10 and 35 degreesC. A tensiometric approach allows for the determination of unimeric solubilities and DeltaG degrees, which is the standard Gibbs free energy change, for the dissolution of phthalates in water. The unimeric solubility of the phthalates increase with decreasing temperature. The DeltaG degrees shows a linear increase with increasing phthalate alkyl chain length. The contribution of enthalpy (DeltaH degrees) and entropy (DeltaS degrees) to DeltaG degrees were calculated from the temperature-dependent solubilities. The contributions of both DeltaH degrees and DeltaS degrees are negative and increase in magnitude with increasing alkyl chain length, suggesting hydrophobic interactions between phthalates and water. The ability of different phthalates to lower the surface tension decreases with increasing alkyl chain length, whereas the relative affinity for adsorption in the air-water interface increases drastically for long-chain phthalates. Despite the low surface activity of phthalates compared with that of common surfactants, they show significant affinity for adsorption in air-water interfaces of natural surface waters. This property, combined with their low solubilities, may affect the fate of these compounds within the natural environment, because they form emulsions above unimeric saturation in aqueous media.
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