期刊
REACTION KINETICS AND CATALYSIS LETTERS
卷 73, 期 2, 页码 283-290出版社
AKADEMIAI KIADO
DOI: 10.1023/A:1014155106147
关键词
m-xylene; isomerization; SAPO-11/HZSM-5 catalyst
The catalytic isomerization of m-xylene was studied over a solid acid silicoaluminophosphate type SAPO-11, mixed to HZSM-5 zeolite. The reaction was processed varying the temperature and weight hourly space velocity, using a fixed bed continuous flow reactor. The m-xylene suffers isomerization to p-xylene and o-xylene by molecular displacement of methyl groups. The mixed catalyst was selective to p-xylene at 623 K and 2.5 h(-1) with a maximum p/o ratio of 2.05. The ethylbenzene formation was not observed in the products. In this process an apparent activation energy of the order of 13.9 kJ mol(-1) was obtained.
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