期刊
COORDINATION CHEMISTRY REVIEWS
卷 211, 期 -, 页码 97-115出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00274-5
关键词
electron-transfer processes: electrochemiluminescence: dendrimers; molecular wires; molecular machines
The investigations carried out in the Bologna group on Ru(bpy)(3)(2+) (bpy = 2,2'-bipyridine) and related systems are reviewed. The following topics are discussed: (i) bimolecular energy and electron-transfer processes (including the measure of the rate of self-exchange energy-transfer); (ii) tuning the excited state properties by changing the ligands (including a caged version of Ru(bpy)(3)(2+)); (iii) chemi- and electrochemiluminescent processes (including the description of an artificial firefly); (iv) photochemistry without light; (v) molecular-level wires for energy and electron transfer: (vi) dendrimers for light harvesting; (vi) light-powered molecular machines. (C) 2001 Elsevier Science B.V. All rights reserved.
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