期刊
CERAMICS INTERNATIONAL
卷 44, 期 17, 页码 21933-21941出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2018.08.306
关键词
Carbon; Fe3O4 nanoparticles; Fe/Fe3O4/C composite microspheres; Electromagnetic wave absorption
资金
- National Natural Science Foundation of China [91326102, 5130, 2049]
- Project of Natural Scientific Research Innovation Foundation in Harbin Institute of Technology [HIT.NSRIF.2015106, HIT.NSRIF.2014129]
- Technology Development Program at Weihai [2013DXGJ12]
Carbon materials have aroused extensive interests for their remarkable electrical properties as electromagnetic wave (EMW) absorption. However, the synthesis of the wide-band electromagnetic wave absorbent is an insuperable challenge for attaining effective refection loss and electromagnetic matching. Herein, a facile method for large-scale synthesis of monodispersed Fe/Fe3O4/C composite microspheres is proposed. The carbon microspheres (1-2 mu m in diameter) imbedded with nanosized Fe/Fe3O4 particles (10-20 nm) are uniformly produced by polymerization and carbothermic reduction processes. The products exhibit the minimum refection loss - 45.5 dB at 9.4 GHz and a broad bandwidth of 4.1 GHz below - 10 dB from 7.8 GHz to 11.9 GHz with a thickness of 3.0 mm. The absorption mechanism indicates a unique deviated Debye dipolar relaxation effect in the absorbing bandwidth.
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