4.4 Article

Multicomponent adsorption of butane, NO2 and SO2 on activated carbon

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ADSORPTION SCIENCE & TECHNOLOGY
卷 20, 期 4, 页码 353-370

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SAGE PUBLICATIONS INC
DOI: 10.1260/02636170260295542

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Dynamic adsorption experiments have been carried out with the help of an FT-help of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorptionhelp of an FT IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorption IR (Fourier-Transform InfraRed) spectrometer. Fixed bed adsorption breakthrough curves were obtained for n-butane, SO2 and NO2 gases as well as for the reaction products NO, N2O and CO2. The adsorption of SO2 and NO2 on activated carbon was studied both during single- and co-adsorption experiments at 30 C. The activated carbon used exhibited a disadvantage towards NO2 adsorption in that it was partly converted to NO and immediately desorbed as NO. A further reaction to N2O could also be observed. The activated carbon was rapidly altered and lost a notable part of its loading capacity as a result of the presence of water and oxygen. During co-adsorption, SO2 reacted with NO2 (both as adsorbed species) and produced an additional amount of NO. An ash-tree spherical activated carbon with an extended surface area (1000 m(2)/g) was used in all experiments.

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