期刊
DYES AND PIGMENTS
卷 52, 期 1, 页码 23-28出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0143-7208(01)00083-3
关键词
photochromism; spiropyran; X-ray crystallography
Photochromic properties of spiroindolinobenzopyrans in which a -(CH2)(3)- or -(CH2)(5)- moiety links the 3-position of indoline and the 3'-position of benzopyran have been studied, In this regard, a photochromic color change was observed only when the -(CH2)(5)- bridging group was used. X-ray crystallographic data showed that the spiro-CO bond length in the pyran ring of the dye containing the -(CH2)(5) bridging group was slightly longer than that in the dye with th -(CH2)(3)-bridging group. X-ray data also suggest that extended conjugation in the open form of the dye containing the -(CH-(2))(3)-bridging group is inhibited because of the fixed conformation of the 6-membered ring. (C) 2002 Elsevier Science Ltd. All rights reserved.
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