期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 6, 期 4, 页码 259-267出版社
SOC PORPHYRINS & PHTHALOCYANINES
DOI: 10.1142/S1088424602000294
关键词
porphyrin; main group element; porphyrin ruffling; boron; tellurium; silicon; tin; phosphorus; arsenic; antimony
Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Group 15 porphyrin complexes are discussed. A systematic variation in the out-of-plane distortion (ruffling) of light element Group 14 and 15 porphyrin complexes has become apparent now that a significant number of structurally characterized examples are at hand. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.
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