期刊
CERAMICS INTERNATIONAL
卷 40, 期 2, 页码 2877-2884出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2013.10.024
关键词
Fe2O3; Fe3O4; FeOOH; Lithium-ion battery; Supercapacitor
资金
- National Natural Science Foundation of China [50872016, 20973033, 51125009]
- National Natural Science Foundation for Creative Research Group [21221061]
- Hundred Talents Program of the Chinese Academy of Sciences
- Changzhou University Overseas Research and Training Program
- Jiangsu Overseas Research and Training Program for University Prominent Young and Middle-aged Teachers and Presidents
Fe-based materials, Fe2O3, Fe3O4, and FeOOH, were synthesized by the microwave-hydrothermal process in the temperature range of 100-200 degrees C and under very short reaction times of 15 min to 2 h. Under microwave-controlled hydrolysis and redox reactions, cube-like Fe2O3 was crystallized using FeCl3, Fe3O4 particles were crystallized from FeCl2 and FeOOH nanorods were crystallized using FeCl3. The Fe-based materials were fabricated to make anodes and cathodes of lithium-ion battery and supercapacitor electrode materials to study their potential electrochemical applications. The electrochemical results showed that FeOOH had better anode capacity as lithium-ion batteries than those of Fe2O3 and Fe3O4. The present results suggest that the microwave-hydrothermally synthesized Fe-based materials are promising lithium-ion battery anode materials. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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