期刊
CERAMICS INTERNATIONAL
卷 39, 期 8, 页码 8833-8839出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2013.04.072
关键词
Porosity; Mechanical properties; Thermal conductivity; Al2O3; Gel casting
资金
- National Natural Science Foundation of China (NSFC) [51172119, 51102140]
Porous alumina ceramics with ultra-high porosity were prepared through combining the gel-casting process with the pore-forming agent technique. Porosity and pore size distribution of the sintered bulks were evaluated with and without adding starch, respectively. In particular, the influences of starch addition on the properties, including thermal conductivity and compressive strength were studied. It was found that the incorporation of starch increased the nominal solid loading in the suspension and subsequently promoted the particle packing efficiency. The porosity is raised with increasing starch content from 0 to 30 vol%, which brings the decrease in thermal conductivity, whereas the compressive strength isn't seriously degraded. The further higher starch addition (40 vol%), however, would deteriorate the performance of the alumina porous ceramics. It is believed that the appropriate starch amount (lower than 30 vol%), working as a pore-forming agent, suppresses the driving force of densification without affecting the connections of neighboring grains while excessive starch amount would lead to the collapse of the porous structure. (C) 2013 The Authors. Published by Elsevier Ltd. All tights reserved.
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