期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 12, 页码 1294-1295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b202898k
关键词
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The ceric(IV) ammonium nitrate (CAN)-mediated radical addition of dimethyl malonate to glycals 1 affords methyl glycosides 2 and ortho esters 3 as main products; the product distribution strongly depends on the substitution pattern at the 1-position, which can be rationalized in terms of the oxidation potentials of the intermediary anomeric radicals.
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