期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 19, 页码 2264-2265出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b206889c
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Treatment of [UO2Cl2( thf)(3)] in thf with one equivalent of [Na{CH(Ph2P = NSiMe3)(2)}] yields an unusual uranyl chloro-bridged dimer containing a uranium( VI)-carbon bond as part of a tridentate bis(iminophosphorano) methanide chelate complex. The methine carbon is displaced significantly from the uranyl equatorial plane.
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