期刊
CEMENT AND CONCRETE RESEARCH
卷 40, 期 11, 页码 1620-1629出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2010.07.004
关键词
Blended cements; Chemical dissolution; Scanning electron microscopy (SEM); Image analysis (IA); Degree of reaction
资金
- COIN, the COncrete INnovation centre
The quantification of the fly ash (FA) in FA blended cements is an important parameter to understand the effect of the fly ash on the hydration of OPC and on the microstructural development. The FA reaction in two different blended OPC-FA systems was studied using a selective dissolution technique based on EDTA/NaOH, diluted NaOH solution, the portlandite content and by backscattered electron image analysis. The amount of FA determined by selective dissolution using EDTA/NaOH is found to be associated with a significant possible error as different assumptions lead to large differences in the estimate of FA reacted. In addition, at longer hydration times, the reaction of the FA is underestimated by this method due to the presence of non-dissolved hydrates and MgO rich particles. The dissolution of FA in diluted NaOH solution agreed during the first days well with the dissolution as observed by image analysis. At 28 days and longer, the formation of hydrates in the diluted solutions leads to an underestimation. Image analysis appears to give consistent results and to be most reliable technique studied. (c) 2010 Elsevier Ltd. All rights reserved.
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