期刊
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
卷 379, 期 -, 页码 89-94出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/713738672
关键词
protonic conduction; coordination polymer; AC conductivity measurement; hydrogen doping; electronic conduction; inorganic-organic hybrids
AC conductivity measurements with an impedance analyzer were carried out for a hydrogen-doped coordination polymer, N,N'-bis-(2-hydroxyethyl)dithiooxamidatocopper(II), in order to estimate the protonic conductivity (sigma(p)). The log sigma(p) was linearly increased from 2.6x10(-9) to 2.2x10(-6) S cm(-1) with relative humidity (RH) from 45 to 100% at 300 K. A slight hysteresis of protonic conductivity was observed upon increasing and decreasing RE, which implies that H3O+ is generated by a reaction between water molecule and acid-base polymer near RH similar to 100%.
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