期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 4, 期 17, 页码 4140-4148出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b204032h
关键词
-
The surface part of the oxygen incorporation reaction into the model material Fe-doped SrTiO3 is investigated by in situ optical spectroscopy. Experiments close to and far from equilibrium ( small and large pO(2) changes) and the effect of UV irradiation on the reaction rate allow us to draw the following conclusions with respect to the kinetic processes at the surface: (i) molecular oxygen species participate in or before the rate determining step (RDS), and (ii) a single conduction band electron participates in or before the RDS of the incorporation reaction even though the bulk is p-type conducting. Probable reaction mechanisms comprising chemisorption, charge transfer, dissociation and oxygen ion transfer steps are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据