期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 4, 期 20, 页码 4855-4865出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b206170h
关键词
-
Infrared (IR) photodissociation spectra of isomeric C3H3+-L dimers with the inert ligands L=Ne, Ar, O-2, N-2, and CO2 are recorded in the spectral range of the C-H stretch fundamentals. At least two C3H3+ isomers are generated by electron impact ionization of allene (H2CCCH2) in the cluster ion source, namely the cyclopropenyl (c-C3H3+) and propargyl (H2CCCH+) cations. Both C3H3+ ions form weakly-bound adducts with all ligands considered and the attraction in these ion ligand complexes is dominated by induction and electrostatic forces. In general, the intermolecular interaction in both c-C3H3+-L and H2CCCH+-L increases in the order Ne
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
© Peeref 2019-2024. All rights reserved.