期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 4, 期 15, 页码 3578-3582出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b202625m
关键词
-
Two-color REMPI and ZEKE photoelectron spectra are presented for the trans-acetanilide Ar complex. Methyl rotor features are prominent in the cluster spectra and appear with unperturbed frequencies and intensities compared to acetanilide, indicating that the argon atom exerts little influence on the methyl rotor from its van der Waals binding position above the aromatic ring. Analysis of the spectra allowed the determination of the S-1 and D-0 barrier heights ( 50 and 320 cm(-1)), and the S-0 and S-1 0a-1e splitting (3.9 and 2.0 cm(-1)).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据