期刊
CELLULOSE
卷 19, 期 3, 页码 695-703出版社
SPRINGER
DOI: 10.1007/s10570-012-9683-7
关键词
Regenerated cellulose film; Alkali/urea; Drying conditions; Oxygen barrier; Mechanical properties
资金
- Japan Society for the Promotion of Science (JSPS) [21228007]
- China Scholarship Council (CSC)
- Grants-in-Aid for Scientific Research [12J07663, 11J03027, 21228007, 23688020] Funding Source: KAKEN
Mechanical, thermal and oxygen barrier properties of regenerated cellulose films prepared from aqueous cellulose/alkali/urea solutions can be markedly improved by controlling the drying conditions of the films. By pre-pressing followed by vacuum drying under compression, the tensile strength, Young's modulus, coefficient of thermal expansion and oxygen permeability of the dried films reached 263 MPa, 7.3 GPa, 10.3 ppm K-1 and 0.0007 ml mu m m(-2) day(-1) kPa(-1), respectively. Thus, films produced in this way show the highest performance of regenerated cellulose films with no orientation of cellulose chains reported to date. These improved properties are accompanied by a clear increase in cellulose II crystallinity from 50 to 62% during pre-pressing/press-vacuum drying process. At the same time, the film density increased from 1.45 to 1.57 g cm(-3), and the moisture content under equilibrium conditions decreased from 14.1 to 9.8%. Hence, the aqueous alkali/urea solvent system has potential applications in producing new and environmentally friendly cellulose films with high performances through control of the drying conditions.
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