期刊
CELLULOSE
卷 18, 期 2, 页码 405-419出版社
SPRINGER
DOI: 10.1007/s10570-010-9476-9
关键词
Regioselective acylation; Cellulose pivalate; Cellulose adamantate; Cellulose 2,4,6-trimethylbenzoate; Mesitoyl cellulose; NMR spectroscopy; Distribution pattern; Regioselective substitution
资金
- ICTAS
- MII at Virginia Tech
The regioselective esterification of cellulose by reaction with bulky acyl halides including pivaloyl chloride, adamantoyl chloride and 2,4,6-trimethylbenzoyl chloride was studied. Functionalization conditions to achieve a given degree of substitution (DS) and the resulting ester substitution pattern were described in detail. One- and two-dimensional NMR spectroscopy techniques were used to confirm the structure of the esters obtained. We compared the effects on substitution of using different esterifying reagents and solvent systems including DMAc/LiCl, DMSO/TBAF, and ionic liquids (ILs).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据