期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 175, 期 -, 页码 47-50出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2015.03.004
关键词
Xenon; Antimony pentafluoride; Nytril; Crystal structure
资金
- Slovenian Research Agency (ARRS) within the research program: Inorganic Chemistry and Technology [P1-0045]
NO2SbF6 crystalizes at 150 K in the orthorhombic Cmmm space group (No. 65) with a = 6.8119(7) angstrom, b = 7.3517(7) angstrom, c = 5.5665(5) angstrom, V = 278.77(5) angstrom(3), and Z = 2. Its crystal structure exhibits a different packing of the [NO2](+) and [SbF6](-) ions than in the known crystal structure of NO2AsF6. The XeF5SbF6 compound is orthorhombic at 150 K, space group Pnma (No. 62), with a = 16.7159(6) angstrom, b = 8.1093(3) angstrom, c = 5.7576(2) angstrom, v = 780.47(5) angstrom(3), Z = 4, and it is isotypic with the known XeF5MF6 crystal structures of M = Nb, Ru, and Pt. The unit cell of XeF5Sb2F11 is triclinic at 200 K, P (1) over bar space group (No. 2), with a = 8.5223(8) angstrom, b = 8.5582(8) angstrom, c = 9.2012(8) angstrom, alpha = 68.799(8)degrees, beta = 74.897(8)degrees, gamma = 76.252(8)degrees, V = 596.35(10) angstrom(3) and Z = 2. Each [XeF5](+) cation has four interactions with the three [Sb2F11](-) anions. (C) 2015 Elsevier B.V. All rights reserved.
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