期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 75, 期 1, 页码 111-121出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.75.111
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Regio- and stereoisomers of 1,2,omega-trimethyldecyl propionate (omega = 5-9) were prepared from stereochemically pure chiral building blocks as sex pheromone candidates of a pine sawfly; Diprion nipponica. Among the synthesized candidates, (1S,2R,8S)-1,2,8-trimethyldecyl propionate was found to be the sex pheromone of D. nipponica, based on compatibility of its GC-MS data with that of the extract of females, and its significantly high pheromone activity in a field bioassay. The field bioassay of the synthesized compounds also revealed that (1S,2R,8R)-1,2,8-trimethyldecyl propionate, (1S,2R,7S)-1,2,7-trimethyldecyl propionate, and (1S,2R,6S)-1,2,6-trimethyldecyl propionate could attract mate sawflies to some extent as pheromone mimics.
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