期刊
PHYTOCHEMISTRY
卷 59, 期 1, 页码 99-104出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0031-9422(01)00433-2
关键词
Artabotrys hexapetalus; Annonaceae; beta-methoxy-gamma-methylene-alpha,beta-unsaturated-gamma-butyrolactones; artapetalins A-C; (+)-tulipalin B; unsaturated fatty acid derivative; biosynthesis; 2D NMR
The dichloromethane extract of the aerial parts of Artabotrys hexapetalus afforded three beta-methoxy-7-methylene-alpha,beta-unsaturated-gamma-butyrolactones, which Lire proposed to be derived from a C-18 unsaturated fatty acid by a biosynthetic route similar to that proposed for the Annonaceous acetogenins. The structure of the unique beta-methoxy-gamma-methylene-substituted, alpha,beta-unsaturated-gamma-butyrolactone ring of artapetalins A-C (1-3) was determined by 2D-NMR spectroscopic analyses. Two unusual simple butyrolactones, (+)-tulipalin B and (2R,3R)- 3-hydroxy-2-methylbutyrolactone were also isolated from this species. (C) 2002 Published by Elsevier Science Ltd.
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