期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 5, 期 1, 页码 28-31出版社
ELSEVIER
DOI: 10.1016/S1387-7003(01)00330-6
关键词
coordination polymer; coordination modes; double-layered structure; lanthanide
Two coordination polymers [La-2(tdga)(3)(H2O)(2)](n) (1) and {[Pr-2 (tdga)(3) (H2O)(2)] (.) H2O}(n) (2) were obtained by the reaction between Ln(OH)(3) (Ln = La, Pr) and thiodiglycolic acid (H(2)tdga = H2S(CH2CO2)(2)). which have a novel double-layered and a single-layered structure, respectively. In the complexes, new coordination modes of the ligand were observed. (C) 2002 Elsevier Science B.V. All rights reserved.
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