Activated carbon prepared from biomass as adsorbent: elimination of Ni(II) from aqueous solution

Activated carbon (AC) prepared from waste Parthenium was used to eliminate Ni(II) from aqueous solution by adsorption. Batch mode adsorption experiments are carried out, by varying contact time, metal ion concentration, carbon concentration, pH and desorption to assess kinetic and equilibrium parameters. They allowed initial adsorption coefficient, adsorption rate constant and maximum adsorption capacities to be computed. The adsorption data were modeled by using both Langmuir and Freundlich classical adsorption isotherms. The adsorption capacity (Q(0)) calculated from the Langmuir isotherm was 54.35 mg Ni(II)/g of AC at initial pH of 5.0 and 20 degreesC, for the particle size 250-500 mum. Increase in pH from 2 to 10 increased percent removal of metal ion. The regeneration by HCl of Ni(II)-saturated carbon by HCl, allowed suggestion of an adsorption mechanism by ion-exchange between metal ion and H+ ions on the AC surfaces. Quantitative recovery of Ni(II) was possible with HCl. (C) 2001 Elsevier Science Ltd. All rights reserved.