Stable carbon and radiocarbon isotope compositions of particle size fractions to determine origins of sedimentary organic matter in an estuary

Stable and radioactive carbon isotopic compositions of particle size fractions of a surface sediment from the Ems-Dollard estuary vary considerably with particle size. The organic material in the fine fractions (<20 mum) has considerably higher C-14 values ((14)a-80%) than that in the coarse fractions (52%) and has higher delta(13)C values (average of -23parts per thousand and -25.6parts per thousand, respectively). This shows that OM in the fine and the coarse fractions has different sources. The organic carbon in the fractions with particle sizes < 20 mum is mainly imported from the North Sea. The contribution of material from the Ems river appears negligible. The carbon isotopic composition of the coarse fractions points to a terrestrial contribution. Discrete organic fragments are found of both terrestrial and marine/estuarine origin. (C) 2002 Elsevier Science Ltd. All rights reserved.