期刊
MACROMOLECULAR RESEARCH
卷 11, 期 6, 页码 458-466出版社
SPRINGER
DOI: 10.1007/BF03218976
关键词
sulfonic acid; polyimides; m-phenylenediamine; 2,2-bis(trifluoromethyl)benzidine; proton conductivity; water insolubility
Several copolyimides have been synthesized with different combinations of comonomers in order to study the relationship between conductivity and water insolubility. m-Phenylenediamine (m-PDA), an angled comonomer, was introduced into the polymer backbone to increase water absorption, and resulted in higher proton conductivity. 2,2-bis(trifluoromethyl)benzidine (TFMB) was used as the comonomer to promote water insolubility. There is a good correlation between the water uptake and conductivity of the polyimides. The copolyimides that had high water uptake also generated high proton conductivity. Those polyimides had good mechanical properties. The copolyimides that have 27 mol% of TFMB and 9 mol% of m-PDA have reasonable conductivities and are insoluble in water at 90degreesC, even though they have lower conductivities than those of the homopolymer.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据