期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 7, 期 4-5, 页码 318-327出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424603000410
关键词
porphyrin; self-assembly; photoinduced energy transfer; photoinduced electron transfer; association constant
An overview of simple methods for the determination, by UV-vis spectroscopy, of association constants of porphyrin based, self-assembling components is presented. Sources of ambiguity and errors are outlined in order to provide non-specialists with basic information. A few cases of self-assembled structures based on porphyrins and displaying photoinduced energy and electron transfer processes are reviewed and evidence is given that a correct determination and interpretation of the association phenomena are of key importance for the interpretation of the photoinduced processes within the array. Copyright (C) 2003 Society of Porphyrins & Phthatocyanines.
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