期刊
JOURNAL OF CARBOHYDRATE CHEMISTRY
卷 22, 期 6, 页码 385-393出版社
TAYLOR & FRANCIS INC
DOI: 10.1081/CAR-120025325
关键词
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Although trimethylsilyl triflate (TMSOTf) has been widely used to promote glycosyl trichloroacetimidates in oligosaccharide synthesis, silver triflate (AgOTf) was proved to be a mild and in some cases more efficient catalyst in TMSOTf-sensitive glycosylations. Migration and degradation in some specific coupling reactions can be reduced significantly under this alternative glycosylation condition.
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