期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 1, 期 12, 页码 2025-2028出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b305189g
关键词
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Since Sharpless' discovery of the asymmetric aminohydroxylation ( AA) reaction, a major challenge for chemists has been to find ways of controlling the regio- and stereochemical outcome of this important reaction. Detailed herein is a review of our novel approach towards gaining reliable and predictable regio- and stereocontrol through the use of a tethered carbamate to promote an intramolecular AA reaction, along with a description of the mechanism proposed for this new methodology.
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