期刊
JOURNAL OF POWER SOURCES
卷 113, 期 1, 页码 81-100出版社
ELSEVIER
DOI: 10.1016/S0378-7753(02)00488-3
关键词
simulation; thermal; lithium-ion battery; polyvinylidene fluoride; binder
Published accounts of abuse testing of lithium-ion cells and components are summarized, including modeling work. From this summary, a set of exothermic reactions is selected with corresponding estimates of heats of reaction. Using this set of reactions, along with estimated kinetic parameters and designs for high-rate batteries, models for the abuse behavior (oven, short-circuit, overcharge, nail, crush) are developed. Finally, the models are used to determine that fluorinated binder plays a relatively unimportant role in thermal runaway. (C) 2002 Elsevier Science B.V. All rights reserved.
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